The Reaction of α, β-Unsaturated Compounds with Carbon Tetrachloride Initiated by Various Initiators
نویسندگان
چکیده
منابع مشابه
Alkylating potential of α,β-unsaturated compounds.
Alkylation reactions of the nucleoside guanosine (Guo) by the α,β-unsaturated compounds (α,β-UC) acrylonitrile (AN), acrylamide (AM), acrylic acid (AA) and acrolein (AC), which can act as alkylating agents of DNA, were investigated kinetically. The following conclusions were drawn: i) The Guo alkylation mechanism by AC is different from those brought about the other α,β-UC; ii) for the first th...
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The 1,4-addition of a monofluoromethyl nucleophile to a variety of alpha,beta-unsaturated compounds has been achieved under mild conditions using either phosphines or potassium carbonate at room temperature. alpha-Substituted fluoro(phenylsulfonyl)methane easily undergoes Michael addition to alpha,beta-unsaturated ketones, esters, nitriles, sulfones, as well as propynoates at room temperature t...
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ژورنال
عنوان ژورنال: Journal of Japan Oil Chemists' Society
سال: 1973
ISSN: 1884-2003
DOI: 10.5650/jos1956.22.298